Haven't seen the movie yet, but sure as hell will have to! In the first picture, the inclusion of the curved wall on the right is pure Willis! They could have shot it "clean", with just the skyline, but that wouldn't be it, would it? The second frame, it's almost metaphysical. Even not being aware of the scene context, the clock above the guy's head and the dead body seem to say "your time will come too". The weighing scale is also symbolic. On the third picture the face on the right stands out.
I wonder why you don't get that much great frames in today's hollywood movies (partial answer is in the "Fight the close ups" thread, which opened my eyes :-) ). However I remember being very impressed with the framing in "Constantine", thought it was really outstanding in the use of negative space and symmetry. And "Flight plan" (while not having a very good plot) was also framed beautifully.
PS. Thanks to the recomendations form this forum, I finally saw "Klute" on dvd. Framing it that one (especially in the beginning of the movie) floored me, too.